Metal–organic framework (MOF)-, covalent-organic framework (COF)-, and porous-organic polymers (POP)-catalyzed selective C–H bond activation and functionalization reactions

Abstract

The review summarizes the state-of-the-art of C–H active transformations over crystalline and amorphous porous materials as new emerging heterogeneous (photo)catalysts.

Three new Zn(ii) coordination polymers for highly selective and sensitive detection of Fe3+

“…5,6 Coordination polymers (CPs), as a kind of multifunctional materials with diverse structures and fascinating topologies, have been applied successively to many fields, such as gas adsorption, drug delivery, catalysis, magnetism, and luminescence. [7][8][9][10][11][12][13][14] In recent years, CPs have been proven to be a class of excellent candidates for luminescent sensors. [15][16][17][18][19][20] Metal ions with d 10 electronic configurations show different coordination numbers and various geometric configurations.…”

Phosphine‐Functionalized Porous Materials for Catalytic Organic Synthesis

“…The application of all three classes of porous materials in C−H activation was reviewed by Daliran et al. although without restriction to phosphine‐containing materials [23] . Kumar et al.…”

“…[21] The solid character of the polymers enables simple separation and recycling by filtration, thereby offering the potential to combine the advantages of homogeneous and heterogeneous catalysis. The effects of confinement on phosphines and their catalytic properties were discussed in detail in a recent review by Orton et al [22] The application of all three classes of porous materials in CÀ H activation was reviewed by Daliran et al although without restriction to phosphine-containing materials [23] . Kumar et al published a review focused on the synthesis and the application of phosphorus-containing POPs in catalysis and organic synthesis.…”

Nanosized Shikonin-Fe(III) Coordination Material for Synergistic Wound Treatment: An Initial Explorative Study

“…Metal coordination may be another strategy to address these limitations, including the formed structures of the metal organic framework 11 (MOF) and metal phenolic network (MPN). 12 A Shik-metal derived nanoplatform can bring the improved dispersity and bioavailability by metal coordination to incorporate abundant amounts of Shik and metal(s).…”