Metal-metal interactions involving metalloporphyrins. 4. A new antiferromagnetic phase of tetraphenylporphinatoiron(III) fluoride

Ia, Cohen; Da, Summerville; S, Ru Su

doi:10.1021/ja00435a012

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Cited by 10 publications

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“…A fluoroborate salt was also shown to be [(TPPFe)2F]BF4, an antiferromagnetic solid. 8 In CH2C12 solution that salt dissociates as [(TPPFe)2F]BF4 -TPPFeF + [TPPFe]4 + BF4-. The earlier work8 also noted that attempted preparations of TPP-FeBF4 always resulted in a product which also contained TPPFeF in various amounts.…”

Section: Sce)mentioning

confidence: 99%

“…Comparison of the cyclic voltammograms indicates that (TPPFe)20 and HBF4 produce a mixture of TPPFeF and TPPFeBF4, as observed earlier. 8 The complexity revealed in the magnetic measurements by Wollman and Hendrickson is due to the presence of a mixture of two compounds, one of which is antiferromagnetic,8 and not because of the presence of any mixed-valence species.…”

Section: Sce)mentioning

confidence: 99%

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