Metal Halide Perovskite Nanocrystals for C–X Activation: Role of Halide Vacancies
Siddharth Singh,
Sumit Sahu,
Diksha Mittal
et al.
Abstract:Metal halide perovskite nanocrystals (NCs) possess immense potential in photocatalysis. However, deciphering the intricate surface chemistry that governs these catalytic processes remains a challenge. This study investigates C−X bond activation with CsPbBr 3 NCs, focusing on elucidating the role of dynamic molecular domains in dictating catalytic activity. By manipulating surface interactions through ligand dynamics, we identify halide vacancies as critical sites for C−X bond activation. A systematic explorati… Show more
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