Asian J Org Chem
 2019
DOI: 10.1002/ajoc.201800683
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Metal‐Free Oxidation of Trichloroacetimidates to Aldehydes

Ji-Cong Lou
1
,
Jianye Li
2
,
Wen-Wu Sun
3
et al.

Abstract: A metal-free oxidation reaction of trichloroacetimidates to aldehydes or ketones with DMSO as an oxidant is reported. The reaction exhibits a broad range of functional group tolerance. Detailed mechanistic studies were performed with the aid of NMR, in situ IR spectroscopy, GC-MS analysis and 18 O-labeling experiments. 4 5 6 7 8

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Oxidation and Reduction

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2023
Organic Reaction Mechanisms Series
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Oxidation and Reduction

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2023
Organic Reaction Mechanisms Series
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Green and Efficient Acquirement of Unsaturated Ether from Direct and Selective Hydrogenation Coupling Unsaturated Aldehyde with Alcohol by Bi-Functional Al-Ni-P Heterogeneous Catalysts

Xu
1
,
Huiqing
2
,
Zhao
3
et al. 2023
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