Metal-free functionalization of SQs: a case of chemoselectivity and what ball-milling has got to do with it?

Bołt, Małgorzata; Hanek, Kamil; Frąckowiak, Dawid; Żak, Patrycja

doi:10.1039/d3qi00625e

Inorg. Chem. Front.

2023

DOI: 10.1039/d3qi00625e

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Metal-free functionalization of SQs: a case of chemoselectivity and what ball-milling has got to do with it?

Małgorzata Bołt

Kamil Hanek

Dawid Frąckowiak³

et al.

Abstract: A new simple, metal-free modification of mercapto-substituted silsesquioxane (SQ-SH) with α,β-unsaturated aldehydes is presented.

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Eco-Friendly Functionalization of Ynals with Thiols under Mild Conditions

Hanek,

Żak

2024

IJMS

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A new eco-friendly method for the synthesis of mono- and multifunctional organosulfur compounds, based on the process between ynals and thiols, catalyzed by bulky N-heterocyclic carbene (NHC), was designed and optimized. The proposed organocatalytic approach allows the straightforward formation of a broad range of thioesters and sulfenyl-substituted aldehydes in yields above 86%, in mild and metal-free conditions. In this study, thirty-six sulfur-based derivatives were obtained and characterized by spectroscopic methods.

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Eco-Friendly Functionalization of Ynals with Thiols under Mild Conditions

Hanek,

Żak

2024

IJMS

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Metal-free functionalization of SQs: a case of chemoselectivity and what ball-milling has got to do with it?

Abstract: A new simple, metal-free modification of mercapto-substituted silsesquioxane (SQ-SH) with α,β-unsaturated aldehydes is presented.

Cited by 1 publication

References 50 publications

Eco-Friendly Functionalization of Ynals with Thiols under Mild Conditions

Eco-Friendly Functionalization of Ynals with Thiols under Mild Conditions

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