Abstract:By the solvothermal reactions of 2,5-bis(1H-1,2,4-triazol-1-yl)terephthalic acid (H 2 L) with transition-metal ions, two novel polymeric complexes, namely, poly-[diaqua[ 4 -2,5-bis(1H-1,2,4-triazol-1-yl)terephthalato]cobalt(II)], [Co(C 12 H 6 - (2), were isolated. Both polymers have been characterized by FT-IR spectroscopy, elemental analysis and single-crystal X-ray diffraction analysis. The complexes have similar two-dimensional layered structures and coordination modes. Furthermore, the two-dimensional laye… Show more
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