“…These products will be interpreted (Discussion Section) as arising from -hydroxyalkyl complex 8. An independent generation of -hydroxyalkyl complex 8 from hydroxyacyl complex 5 was attempted (Scheme II). Treatment of 5 with (CH3)3N+-0~u nder conditions that successfully decarbonylated (silyloxy)acyl complex 4 (27) (a) Shvo, Y.; Hazum, E. J. Chem. Soc., Chem.…”
Section: Resultsmentioning
confidence: 99%
“…(B) A 5-mm septum-capped NMR tube was charged with 6 (0.058 g, 0.145 mmol). THF-<f8 (0.5 mL), and 1, 2,4,5-tetrachlorobenzene internal standard. The sample was cooled at -10 °C in a NMR probe.…”
“…These products will be interpreted (Discussion Section) as arising from -hydroxyalkyl complex 8. An independent generation of -hydroxyalkyl complex 8 from hydroxyacyl complex 5 was attempted (Scheme II). Treatment of 5 with (CH3)3N+-0~u nder conditions that successfully decarbonylated (silyloxy)acyl complex 4 (27) (a) Shvo, Y.; Hazum, E. J. Chem. Soc., Chem.…”
Section: Resultsmentioning
confidence: 99%
“…(B) A 5-mm septum-capped NMR tube was charged with 6 (0.058 g, 0.145 mmol). THF-<f8 (0.5 mL), and 1, 2,4,5-tetrachlorobenzene internal standard. The sample was cooled at -10 °C in a NMR probe.…”
“…69-112, 169 (1) C(H,2)-P(1)-C (12,3) 99.9-100.8 ( 3 the methyl complex 9 in good yield, free of other products (see Experimental Section). Likewise, the reaction of compound 13 with acid gives the methyl compound 14 with no observable byproducts.…”
Syntheses and Reactions of a Cationic Hydrido(hydroxymethyl)iridium Complex. The Crystal and Molecular Structure of Hydrido(hydroxy methyl)tetrakis(trimethy Iphosphine) iridium (III) Hexafluorophosphate, [IrH(CH2OH)(PMe3)4][PF6p
“…The only other -hydroxyalkyl metal compound reported was (C5H5)Fe(CO)2[C(CF3)2OH], which was synthesized by Stone from (CsH5)Fe(CO)2-and hexafluoroacetone. 25 Gladysz has attempted generation of (CO)sMnCH(OH)C6H5 by two different routes but found that the presumed intermediate was not observable even at -50 °C and only benzaldehyde and HMn(CO)s could be detected. 17 Pruett proposed hydroxymethyl-and 1,2-dihydroxyethylrhodium intermediates in the rhodium cluster catalyzed conversion of CO/H2 mixtures into ethylene glycol.26 Feder has suggested hydroxymethylcobalt species as precursors of methanol in the cobalt carbonyl catalyzed reduction of CO by H2.…”
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.