Metal-controlled assembly tuning the topology and dimensionality of coordination polymers of Ag(I), Cd(II) and Zn(II) with the flexible 2-(1H-imidazole-1-yl)acetic acid (Hima)

Diaquabis(2,2′-biimidazole)cobalt(II) 4,4′-dicarboxybiphenyl-3,3′-dicarboxylate

“…For a highly porous metal-organic framework with a benzenedicarboxylate linker, see: Li et al (1999). For coordination polymers of Ag(I), Cd(II) and Zn(II) with the flexible 2-(1Himidazole-1-yl)acetic acid linker, see: Wang et al (2007). For the structure of 1,1 0 -biphenyl-2,3,3 0 ,4 0 -tetracarboxylic acid monohydrate and related structures cited therein, see: Jiang et al (2008).…”

“…Data collection: APEX2 (Bruker, 2004); cell refinement: SAINT-Plus (Bruker, 2001); data reduction: SAINT-Plus; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL. only for their intriguing structural motifs (Wang et al 2007), but also for their potential applications, e. g. as organicinorganic hybrid materials (Hagrman et al, 1999), highly porous metal-organic framework (Li et al, 1999), magnetochemistry (Jia et al, 2007). In contrast, the two ionic components of the title structure interact with N-H As shown in Fig.…”

Poly[[aqua(μ-4,4′-bipyridyl-κ2N:N′)bis(μ-formato-κ2O:O′)iron(II)] tetrahydrate]

“…For the potential applications of metal-organic frameworks, see: Jia et al (2007); Hagrman et al (1999); Kortz et al (2003); Li et al (1996); Liu et al (2007); Seo et al (2000); Wang et al (2007); Yaghi et al (1998). Hydrogen-bond geometry (Å , ).…”

catena-Poly[[bis(p-toluenesulfonato-κO)palladium(II)]bis(μ-1,3-di-4-pyridylpropane-κ2N:N′)]

“…Design and construction of metal-organic frameworks (MOFs) have attracted considerable attention in recent years, not only for their intriguing structural motifs but also for their potential applications in the areas of catalysis, separation, gas absorption, molecular recognition, nonlinear optics, and magnetochemistry (Jia et al (2007); Li et al (1996); Seo et al (2000); Hagrman et al (1999); Yaghi et al (1998); Kortz et al (2003); Liu et al (2007); Wang et al (2007)). A successful strategy for the design and synthesis of predictable MOFs is the assembly reaction between metal ions and well designed organic ligands.…”