Metal–biomolecule frameworks (MBioFs)

Imaz, Inhar; Rubio-Martínez, Marta; An, Jihyun; Solé-Font, Isabel; Rosi, Nathaniel L.; Maspoch, Daniel

doi:10.1039/c1cc11202c

Cited by 389 publications

(285 citation statements)

References 127 publications

(79 reference statements)

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“…Advantages of amino acids are their natural framework with rich functional groups, which is amenable to derivatization thereby offering intriguing topologies when inserted as building blocks in supramolecular hierarchical self-assemblies [34][35][36][37][38][39][40][41][42][43][44][45][46][47][48][49][50][51]. Indeed, thanks to their genuine chirality (except glycine) and electronic asymmetry, amino acid derivatives are considered as a preeminent choice to introduce asymmetry in MOFs to direct the network construction.…”

Section: Introductionmentioning

confidence: 99%

“…Among them the perceptible appearance of amino acid derivatives in recent years, either as metal-based molecular entities or oligomeric scaffolds in MOFs or CPs, justify their inclusion in the synthon/tecton library [34][35][36][37][38][39][40][41][42][43][44][45][46][47][48]. In this frame, structure and reactivity of different amino acids in their natural or derivatized form were extensively studied.…”

Section: Introductionmentioning

confidence: 99%

“…were also conducted because of their various binding and bridging modes [26][27][28][29][30][31][32][33]. Not surprisingly, in a short course, biomolecules and natural products like amino acids [34][35][36][37][38][39][40][41][42][43][44][45][46], peptides [47], proteins [46], nucleobases [48], magnesium formates [49], carbohydrates [47], metal glutarates [50,51], γ-cyclodextrin [36] leaped into this mainstream as attractive precursors and soon tributaries like metal-peptide frameworks (MPFs) [47], metal-biomolecule frameworks (MBioFs) [46][47][48] surfaced out and established their niche.…”

Section: Introductionmentioning

confidence: 99%

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Coordination Polymers and Metal Organic Frameworks Derived from 1,2,4-Triazole Amino Acid Linkers

et al. 2011

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Abstract:The perceptible appearance of biomolecules as prospective building blocks in the architecture of coordination polymers (CPs) and metal-organic frameworks (MOFs) are redolent of their inclusion in the synthon/tecton library of reticular chemistry. In this frame, for the first time a synthetic strategy has been established for amine derivatization in amino acids into 1,2,4-triazoles. A set of novel 1,2,4-triazole derivatized amino acids were introduced as superlative precursors in the design of 1D coordination polymers, 2D chiral helicates and 3D metal-organic frameworks. Applications associated with these compounds are diverse and include gas adsorption-porosity partitioning, soft sacrificial matrix for morphology and phase selective cadmium oxide synthesis, Fe II spin crossover materials, zinc-β-lactamases inhibitors, logistics for generation of chiral/non-centrosymmetric networks; and thus led to a foundation of a new family of functional CPs and MOFs that are reviewed in this invited contribution.

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Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

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Coordination Polymers and Metal Organic Frameworks Derived from 1,2,4-Triazole Amino Acid Linkers

et al. 2011

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“…Within a project on the determination of electron density in building blocks 7 of metal organic frameworks 8 , in particular metal bio-organic frameworks (M-Bio-F), 9 we are studying hydrogen bonded networks formed by amino acids in co-crystals or salts, precursors of the MBio-F's. During this research we came across an interesting species: L-histidinium hydrogen oxalate (1), first characterized at ambient conditions by Prabu et al 10 1 has attracted our attention because of its molecular and supramolecular arrangement.…”

Section: Introductionmentioning

confidence: 99%

Correlation between Accurate Electron Density and Linear Optical Properties in Amino Acid Derivatives:l-Histidinium Hydrogen Oxalate

Chimpri

Gryl

Santos

et al. 2013

Crystal Growth & Design

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The accurate electron density and the linear optical properties of L-histidinium hydrogen oxalate are discussed in this paper. Two high resolution single crystal X-ray diffraction experiments were performed and compared with density functional calculations in the solid state as well as in the gas phase. The crystal packing and the hydrogen bond network are accurately investigated using topological analysis based on Quantum Theory of Atoms in Molecules, Hirshfeld surface analysis and electrostatic potential mapping. This compound also offers the possibility to test the electron density building block approach for material science and different refinement schemes for accurate positions and displacement parameters of hydrogen atoms, in the absence of neutron diffraction data.

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“…Both exogenous (not intervening in the body cycles) and endogenous (constitutive part of body composition) linkers have been used in MOF synthesis for drug delivery, with the first group having a higher prevalence [21,[25][26][27][28][29]57]. It is also worth noting that if the therapeutic molecule is directly used as a linker, no large pores are required and the release of the drug molecule is achieved directly through the degradation of the solid, without any side effects arising from the release of a non-active ligand [26,52].…”

Section: Designmentioning

confidence: 99%

Bio-Inspired Metal-Organic Frameworks in the Pharmaceutical World: A Brief Review

André¹,

Quaresma²

2016

Metal-Organic Frameworks

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One of the great challenges in the pharmaceutical industry is the search for more efficient and cost-effective ways to store and deliver existing drugs. Bio-inspired metalorganic frameworks (BioMOFs) are groundbreaking materials that have recently been explored for drug storage, delivery and controlled release as well as for applications in imaging and sensing for therapeutic and diagnostic. This review presents a brief overview on these materials, and by alluding to a few reported examples, it intends to clearly show the extremely important role that BioMOFs have been playing in the pharmaceutical field.

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Metal–biomolecule frameworks (MBioFs)

Cited by 389 publications

References 127 publications

Coordination Polymers and Metal Organic Frameworks Derived from 1,2,4-Triazole Amino Acid Linkers

Coordination Polymers and Metal Organic Frameworks Derived from 1,2,4-Triazole Amino Acid Linkers

Correlation between Accurate Electron Density and Linear Optical Properties in Amino Acid Derivatives:l-Histidinium Hydrogen Oxalate

Bio-Inspired Metal-Organic Frameworks in the Pharmaceutical World: A Brief Review

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