The carbon fiber-ZrO 2 (CF-ZrO 2 ) hybrid was prepared through one-step hydrothermal method, which well realized the synergistic enhancement of CF and ZrO 2 nanoparticles on the wear-resistant performance of polyimide (PI) composites. Results showed that the ZrO 2 nanoparticles were tetragonal and monoclinic mixed phase. The average particle size was about 10 nm. And they were in-situ synthesized on the surface of CF, which endowed CF with much rougher surface and further improved the interfacial adhesion of PI composite. Moreover, the CF-ZrO 2 hybrid reinforced PI composite possessed higher shore hardness and thermal stability than those of PI or its composite reinforce with single CF because of CF with good compressive strength and ZrO 2 with outstanding thermal property. In addition, the anti-wear properties of the PI were greatly improved by filling CF-ZrO 2 hybrid, which was mainly because CF as the main bearing phase of the friction surface of the composites