“…To improve the efficiency of the hydrogen production, researchers work hard on modifying the nanomaterials [3,4,5,6]. Moreover, doping rare metals on semiconductor nanomaterials, changing the morphology of the nanomaterials and synthesis of complex nanomaterials are hot means that can be employed to improve the photocatalytic activity [7,8,9,10,11,12,13,14,15,16,17,18]. Maeda studied the photocatalytic activity of Rutile TiO 2 doped by Ru, Rh, Ir, Pt or Au, with the results showing that the most water splitting amount of H 2 and O 2 for 4 h is 56.6 μmol and 26.5 μmol, respectively, when Pt doping amount is at 1 wt.…”
p-Co3O4/n-TiO2 nanoparticles (~400 nm) for photocatalysis were prepared via carbon assisted method and sol-gel method in this work. The paper also studied the application of visible light illuminated p-Co3O4/n-TiO2 nanocomposites cocatalyst to the overall pure water splitting into H2 and O2. In addition, the H2 evolution rate of the p-Co3O4/n-TiO2 nanocomposites is 25% higher than that of the pure Co3O4 nanoparticles. Besides, according to the results of the characterizations, the scheme of visible light photocatalytic water splitting is proposed, the Co3O4 of the nanocomposites is excited by visible light, and the photo-generated electrons and holes existing on the conduction band of Co3O4 and valence band of TiO2 have endowed the photocatalytic evolution of H2 and O2 with higher efficiency. The optimal evolution rate of H2 and O2 is 8.16 μmol/h·g and 4.0 μmol/h·g, respectively.
“…To improve the efficiency of the hydrogen production, researchers work hard on modifying the nanomaterials [3,4,5,6]. Moreover, doping rare metals on semiconductor nanomaterials, changing the morphology of the nanomaterials and synthesis of complex nanomaterials are hot means that can be employed to improve the photocatalytic activity [7,8,9,10,11,12,13,14,15,16,17,18]. Maeda studied the photocatalytic activity of Rutile TiO 2 doped by Ru, Rh, Ir, Pt or Au, with the results showing that the most water splitting amount of H 2 and O 2 for 4 h is 56.6 μmol and 26.5 μmol, respectively, when Pt doping amount is at 1 wt.…”
p-Co3O4/n-TiO2 nanoparticles (~400 nm) for photocatalysis were prepared via carbon assisted method and sol-gel method in this work. The paper also studied the application of visible light illuminated p-Co3O4/n-TiO2 nanocomposites cocatalyst to the overall pure water splitting into H2 and O2. In addition, the H2 evolution rate of the p-Co3O4/n-TiO2 nanocomposites is 25% higher than that of the pure Co3O4 nanoparticles. Besides, according to the results of the characterizations, the scheme of visible light photocatalytic water splitting is proposed, the Co3O4 of the nanocomposites is excited by visible light, and the photo-generated electrons and holes existing on the conduction band of Co3O4 and valence band of TiO2 have endowed the photocatalytic evolution of H2 and O2 with higher efficiency. The optimal evolution rate of H2 and O2 is 8.16 μmol/h·g and 4.0 μmol/h·g, respectively.
“…For instance, xylene is a harmful organic compound that not only irritates eyes, nose, skin and respiratory system, but also induces serious symptoms such as headaches, fatigue, dizziness, rapid heart rate and unconsciousness even at low concentration. 1,2 Toluene and xylene come from various materials including building materials, paints, aerosols, disinfectants, air fresheners and automotive parts. Metal oxide semiconductor based gas sensors have attracted considerable attention because of their high portability, simplicity of use and low cost, and have previously been used to realize real-time monitoring of toluene and xylene.…”
The development of highly active, sensitive and durable gas sensing materials for the detection of volatile organic compounds (VOCs) is extremely desirable in gas sensors. Herein, a series of mesoporous hierarchical Co3O4-TiO2 p-n heterojunctions have been prepared for the first time via the facile thermal conversion of hierarchical CoTi layered double hydroxides (CoTi-LDH) precursors at 300-400 ºC. The resulting Co3O4-TiO2 nanocomposites showed superior sensing performance towards toluene and xylene in comparison with Co3O4 and TiO2 at low temperature, and the sample with a Co/Ti molar ratio of 4 shows optimal response (Rg/Ra = 113, Rg and Ra denote the sensor resistance in a target gas and in air, respectively) to 50 ppm xylene at 115 ºC. The ultrahigh sensing activity of theses Co3O4-TiO2 p-n heterojunctions originates from their hierarchical structure, high specific surface area (>120 m 2 g −1 ), and the formation of numerous p-n heterojunctions, which results in full exposure of active sites, easy adsorption of oxygen and target gases, and large modulation of resistance. Importantly, hierarchical Co3O4-TiO2 heterojunctions possess advantages of simple preparation, structural stability, good selectivity and long-term durability. Therefore, this work provides a facile approach for the preparation of hierarchical Co3O4-TiO2 p-n heterojunctions with excellent activity, sensitivity and durability, which can be used as a promising material for the development of high-performance gas sensors.
“…Compared with Al-ZnO with different morphologies, the gas response of the macro-/nanoporous ZnO [14,15] is better than that of porous ZnO flakes (prepared by microwave hydrothermal method and one-step hydrothermal method) [32,33], later comes the Al-ZnO films (prepared by cosputtering on a glass substrate) [34] and nanoparticles. Liu.…”
Section: Gas Sensing Property Of the As-synthesized Macro-/nanoporousmentioning
confidence: 99%
“…As we all know, the electrical conductivity of sensors is related to the gas species, operating temperature and relative humidity [14,15,30]. First, the gas response of sensors was tested from 260 to 420 • C at a relative humidity of 30%.…”
Section: Gas Sensing Property Of the As-synthesized Macro-/nanoporousmentioning
confidence: 99%
“…As gas sensor material, zinc oxide and its composite materials show high gas response and excellent selectivity to the reducing gases, such as volatile organic compounds (VOCs) [10][11][12][13][14], toxic or flammable gases [15]. A majority of researches have reported that doping chemical elements such as Ni, Mn, Al, Bi, Cr and Pr in hexagonal wuritzite ZnO can promote its selectivity and response to objective gases [16], change the crystalline state [13], and improve electrical conductivity [17].…”
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