The kinetics of Hg chlorination (with HCl) was studied using a flow reactor system with an online Hg analyzer, and speciation sampling using a set of impingers. Kinetic parameters, such as reaction order (α), overall rate constant (k′ ), and activation energy (E a ), were estimated based on the simple overall reaction pathway. The reaction order with respect to C Hg , k′, and E a were found to be 1.55, 5.07 × 10 -1 ], and 16.13 [kJ/ mol], respectively. The effect of chlorine species (HCl, CH 2 Cl 2 ) on the in situ Hg capture method previously developed 28 was also investigated. The efficiency of capture of Hg by this in situ method was higher than 98% in the presence of chlorine species. Furthermore, under certain conditions, the presence of chlorine enhanced the removal of elemental Hg by additional gas-phase oxidation.