Mercury species in chloroaluminate melts. Characterization of the new ion Hg32+

Benzene Complexes of Ruthenium(II)

“…The structure of the mercury-containing moiety is unknown, but may involve a linear Hg3' group (19)(20)(21), in which the mercury would have the formal oxidation state +2/3. By analogy with other compounds containing this unusual cation (19)(20)(21), a reasonable structure for the complex would be 4.…”

“…By analogy with other compounds containing this unusual cation (19)(20)(21), a reasonable structure for the complex would be 4.…”

Electroanalytical Chemistry in Molten Salts—A Review of Recent Developments

“…In order to minimize or eliminate such problems and still obtain well-defined --.r--shaped voltammograms, one may resort to the use of a rotating disc electrode, (22) apply pulse polarography, (23) or construct the voltammogram from current-time curves. (18,19,24,25) The second approach is probably the simplest to implement, assuming a pulse polarograph is available.…”

“…Recently we have reinvestigated the system in AICla-NaCI melts. (18) In the melt saturated with NaCl (basic) only two voltammetric waves of equal height were obtained. In more acidic melts and at low temperatures the voltammogram indicated an intermediate oxidation state, Hg~+, between Hg~+ and Hg.…”

Thermodynamics of Room Temperature Ionic Liquid BMIInCl4

“…Where (ref) Torsi(1971Torsi( ,10,1900Torsi( -1902 Through a series of the substitution of equation into equation, a pCl-electrode was yield.Hence, in this case, working electrode in the cell may be used as a pCl-one. Our purpose in the paper is to calculate the dissociation constant K and to obtain the dependence of pK on T. Considering the dissociation reaction, other thermodynamic quantities were obtained.…”