Memory Effect on the Synthesis of Perovskite-Type Li-Ion Conductor LixLa2/3–x/3TiO3 (LLTO)
Matthew S. Chambers,
Jiadong Chen,
Robert L. Sacci
et al.
Abstract:The structural chemistry of the solid ion-conducting Li x La 2/3−x/3 TiO 3 (LLTO) is rich with various polymorphs related to atomic segregation. We explored the LLTO reaction pathway from various structurally related precursors (La 2 LiO 3 H, Li 2 TiO 3 , and Li 4 Ti 5 O 12 ), focusing on the effects of LLTO-like structural motifs in precursors using a combination of experimental and computational techniques. Density functional theory (DFT) calculations revealed that the failure of syntheses to produce LLTO be… Show more
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