Black phosphorus (bP) is a crystalline
material that can be seen
as an ordered stacking of two-dimensional layers, which results in
outstanding anisotropic physical properties. The knowledge of its
pressure (P)–temperature (T) phase diagram, and in particular, of its melting curve is fundamental
for a better understanding of the synthesis and stability conditions
of this element. Despite the numerous studies devoted to this subject,
significant uncertainties remain regarding the determination of the
position and slope of its melting curve. Here we measured the melting
curve of bP in an extended P, T region
from 0.10(3) to 5.05(40) GPa and from 914(25) to 1788(70) K, using
in situ high-pressure and high-temperature synchrotron X-ray diffraction.
We employed an original metrology based on the anisotropic thermoelastic
properties of bP to accurately determine P and T. We observed a monotonic increase of the melting temperature
with pressure and the existence of two distinct linear regimes below
and above 1.35(15) GPa, with respective slopes of 348 ± 21 and
of 105 ± 12 K·GPa–1. These correspond
to the melting of bP toward the low-density liquid and the high-density
liquid, respectively. The triple point at which solid bP and the two
liquids meet is located at 1.35(15) GPa and 1350(25) K. In addition,
we have characterized the solid phases after crystallization of the
two liquids and found that, while the high-density liquid transforms
back to solid bP, the low-density liquid crystallizes into a more
complex, partly crystalline and partly amorphous solid. The X-ray
diffraction pattern of the crystalline component could be indexed
as a mixture of red and violet P.