Melt compounding of rigid PVC formulations with hydrotalcites

Abstract

Hydrotalcites, compounds of magnesium-aluminium-hydroxycarbonate, are promoted as environmentally safe materials for costabilisation of PVC products. Commercial grades of hydrotalcites have been added to rigid PVC formulations, containing a range of different stabiliser types, to evaluate their contribution to heat stability and their effect on mechanical properties. Hydrotalcites are confirmed to be effective costabilisers for rigid PVC: static thermal stability (through oven testing) and dynamic thermal stability (via torque rheometry) of PVC compounds are modified by their presence. The extent of change is determined by the primary stabiliser type and the grade of the hydrotalcite. Detailed analysis of mechanical properties has been carried out on compression moulded samples and on extruded compounds. With the former, no significant change in tensile or impact performance was observed, for hydrotalcite levels up to 5 phr. Charpy impact data on extruded PVC have shown significant increase in performance of compounds containing an acrylate modifier when hydrotalcites are used.

Hydrotalcites in Construction Materials

“…The most common minerals of the hydrotalcite group are listed in Table 1. Hydrotalcites have found the greatest practical use in the production and processing of polymers, especially as part of thermal stabilizing compounds for the processing of PVC, neutralizing additives, and flame retardants [3][4][5]. They find a very wide range of applications in heterogeneous catalysis, particularly as precursors for the synthesis of catalysts based on mixed oxides.…”