The goal of this investigation is connected with wishes to use the melanin for formulating the solid polymer electrolyte without the binder for Li batteries. Nature and properties of solid polymer electrolyte of the Li batteries is an important factor for ensuring the properties of Li batteries. For successful optimization the properties of Li batteries the following list includes the important requirements for the polymer electrolyte: high conductivity in wide operating temperature, chemical stability and no ignition at under high temperature - even more than 1000C, low impedance of interface between electrode and solid polymer electrolyte, special design of system - the solid polymer electrolyte in porous structure of electrode. For developing the solid polymer electrolyte without the binder we fulfill this goal includes the melanin in the solid polymer electrolyte.