Mediating Distribution of Magnetic Co Ions by Surfactant in Co-Doped SnO<SUB>2</SUB> Nanorods

Abstract

We demonstrate a method to control the distribution of magnetic Co ions in Co-doped SnO2 nanorods by the surfactant. The nanorods with nanoflower morphology have been synthesized by surfactant-assisted hydrothermal method. The X-ray absorption fine structure spectra at Co K-edge reveal that Co ions substitute for Sn site in SnO2 lattice. The X-ray absorption fine structure spectra at O K-edge with its simulated spectra have been performed to investigate the local environment of Co ions. In the experimental spectra, the pre-edge peak continues to decline with the addition of the surfactant. It shows the same trend when the number of clustered Co ions in the simulated spectra is reduced, which indicates that the surfactant suppresses the formation of Co clusters. The effect of surfactant in mediating Co distribution arises from the strong interactions between the Co2+ ions and the CTA+ ions. In the Co K-edge experimental spectra, the weakened pre-edge peak reflects the electron transfer from the CTA+ ions to Co 3d band. Such electron transfer changes the charge state of Co ions and modifies the electrostatic interactions among dopant ions, leading to the uniform distribution of substitutional Co dopants. These results provide experimental guidance in the synthesis of the homogeneous-doped metal oxide semiconductors.

Unraveling the Core–Shell Structure of Ligand-Capped Sn/SnOx Nanoparticles by Surface-Enhanced Nuclear Magnetic Resonance, Mössbauer, and X-ray Absorption Spectroscopies

“…X-ray absorption spectroscopy (XAS) allows the study of the local electronic and geometric structure (up to 6 Å) around Sn atoms. XAS is an element-specific technique that does not rely on long-range order and has been extensively used to study nanostructured Sn-oxide materials. − The X-ray absorption near edge structure (XANES) spectrum (−50 to 100 eV around the absorption edge) corresponds to the empty density of p states and, therefore, provides information about the structure, the oxidation state, and the site symmetry. Background-corrected and normalized Sn K-edge XANES spectra for 10 and 18 nm Sn/SnO x NPs are presented along with the reference, commercially available powders of Sn, SnO, and SnO 2 (Figure ).…”