Mediated Surface Properties of Polybenzoxazines

Mohamed, Malahah; Lin, Ruey-Chorng; Hsu, Kuo-Chih; Zhang, W.; Xin, Zhong; Kuo, Shiao‐Wei

doi:10.1016/b978-0-12-804170-3.00012-3

Cited by 2 publications

(1 citation statement)

References 65 publications

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“…3,29 Benzoxazine (BZ) monomers possess the ability to undergo thermal ring-opening polymerization, without the need for any catalysts and without the formation of byproducts, forming polymers with several unique features (e.g., high chemical resistance, low surface free energy, high ame retardancy) that have drawn the attention of both academia and industry. [30][31][32][33][34][35][36][37] Triphenylamine (TPA) possesses a unique two-photon absorption ability and has been studied and applied in many elds, including optoelectronic devices and electron transition devices. [38][39][40] Hence, we have been interested in combining the properties of BZ and TPA units in polymeric systems.…”

Section: Introductionmentioning

confidence: 99%

Well-defined benzoxazine/triphenylamine-based hyperbranched polymers with controlled degree of branching

Lin

Kuo

2018

RSC Adv.

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Section: Introductionmentioning

confidence: 99%

Well-defined benzoxazine/triphenylamine-based hyperbranched polymers with controlled degree of branching

Lin

Kuo

2018

RSC Adv.

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Benzoxazine/Triphenylamine‐Based Dendrimers Prepared through Facile One‐Pot Mannich Condensations

Lin

Mohamed

Kuo

2017

Macromol. Rapid Commun.

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A series of thermally polymerizable dendrimers of various generations, equipped with triphenylamine (TPA) and benzoxazine (BZ) groups, is synthesized through facile one-pot Mannich condensations of N ,N -bis(4-aminophenyl)benzene-1,4-diamine (TPA-3NH , as the core group), 4-(bis(4-aminophenyl)amino)phenol (TPA-2NH -OH, as the AB branching group), and CH O in 1,4-dioxane. The ratios of the integrated areas in the H nuclear magnetic resonance spectra of these dendrimers are consistent with the theoretical numbers of protons, suggesting their successful syntheses. Bathochromic shifts of signals are evident in the UV-vis and photoluminescence spectra upon increasing the generation of the TPA-BZ dendrimers, consistent with an increase in the effective conjugation length. The TPA-BZ dendrimers are able to undergo thermal polymerization and display unique optical physical properties, resulting in thermoset TPA networks after thermal ring-opening polymerization.

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Mediated Surface Properties of Polybenzoxazines

Cited by 2 publications

References 65 publications

Well-defined benzoxazine/triphenylamine-based hyperbranched polymers with controlled degree of branching

Well-defined benzoxazine/triphenylamine-based hyperbranched polymers with controlled degree of branching

Benzoxazine/Triphenylamine‐Based Dendrimers Prepared through Facile One‐Pot Mannich Condensations

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