Mechanosynthesis of pentiptycene-based polyesters and polycarbonates
Wahab A.K. Al-Ithawi,
Eman S. A. Al-Sammarraie,
Artem V. Baklykov
et al.
Abstract:Iptycenes are common building blocks for the small-molecules or polymer-based chemosensors and fluorophores. In addition, iptycene derivatives are widely presented in polymers of intrinsic microporosity (PIMs) as materials for the separation and purification technologies. In this manuscript we wish to report a mechanochemical approach to pentiptycene-based polyesters and polycarbonates as, possibly, new representatives of PIMs. Our approach involves the polycondensation reaction between 5,7,12,14-tetrahydro-5,… Show more
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