2014
DOI: 10.1039/c4tc01639d
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Mechanofluorochromic behaviors of β-iminoenolate boron complexes functionalized with carbazole

Abstract: New β-iminoenolate boron complexes exhibit different mechanofluorochromic properties due to the excimer and monomer transformation.

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Cited by 103 publications
(43 citation statements)
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“…S10 and S11). Both of the bifunctionalized polymer networks showed very similar adsorption selectivities of 4.0 for CO 2 /CH 4 and 30 for CO 2 /N 2 at 273 K. The CO 2 / N 2 adsorption selectivity by both of the polymer networks is comparable to that of some other MOPs under the similar conditions, such as the triazine-functionalized CMPs (9.0e25.2 at 298 K) [50], the amide-functionalized CMPs (8.5e12 at 298 K) [26], the imine-linked porous polymer frameworks (14.5e20.4 at 273 K) [52], the carbazolic porous organic frameworks (19À37 at 273 K) [58], and the nanoporous azo-linked polymers (30e43 at 273 K) [34], though it is lower than that of some other reported MOPs with the CO 2 /N 2 adsorption selectivity higher than 100, such as the azobridged covalent organic polymer of Azo-COP-2 with a CO 2 /N 2 adsorption selectivity of 109 at 273 K [59], the porous benzimidazole-linked polymer of BILP-2 with a CO 2 /N 2 adsorption selectivity of 113 at 273 K [48], the PPN-6-SO 3 NH 4 with a CO 2 /N 2 adsorption selectivity of 196 at 295 K, and the tri(4-ethynylphenyl) amine-based porous aromatic framework with amine groups of PAF-33eNH 2 with the CO 2 /N 2 adsorption selectivity as high as 250 at 273 K [29]. However, the absolute amount of CO 2 adsorbed was only 1.19 mmol g À1 for PAF-33eNH 2 at 273 K/1.0 bar [29], much lower than that of the BFCMP-2 (2.77 mmol g À1 at 273 K/1.13 bar) in this work.…”
Section: Resultsmentioning
confidence: 98%
“…S10 and S11). Both of the bifunctionalized polymer networks showed very similar adsorption selectivities of 4.0 for CO 2 /CH 4 and 30 for CO 2 /N 2 at 273 K. The CO 2 / N 2 adsorption selectivity by both of the polymer networks is comparable to that of some other MOPs under the similar conditions, such as the triazine-functionalized CMPs (9.0e25.2 at 298 K) [50], the amide-functionalized CMPs (8.5e12 at 298 K) [26], the imine-linked porous polymer frameworks (14.5e20.4 at 273 K) [52], the carbazolic porous organic frameworks (19À37 at 273 K) [58], and the nanoporous azo-linked polymers (30e43 at 273 K) [34], though it is lower than that of some other reported MOPs with the CO 2 /N 2 adsorption selectivity higher than 100, such as the azobridged covalent organic polymer of Azo-COP-2 with a CO 2 /N 2 adsorption selectivity of 109 at 273 K [59], the porous benzimidazole-linked polymer of BILP-2 with a CO 2 /N 2 adsorption selectivity of 113 at 273 K [48], the PPN-6-SO 3 NH 4 with a CO 2 /N 2 adsorption selectivity of 196 at 295 K, and the tri(4-ethynylphenyl) amine-based porous aromatic framework with amine groups of PAF-33eNH 2 with the CO 2 /N 2 adsorption selectivity as high as 250 at 273 K [29]. However, the absolute amount of CO 2 adsorbed was only 1.19 mmol g À1 for PAF-33eNH 2 at 273 K/1.0 bar [29], much lower than that of the BFCMP-2 (2.77 mmol g À1 at 273 K/1.13 bar) in this work.…”
Section: Resultsmentioning
confidence: 98%
“…5,6 It is well-known that phosphates possess many excellent properties as phosphor hosts, i.e. Recently, many novel Eu 3+ -doped compounds have been reported as promising candidates as potential red-emitting phosphors for LED application.…”
Section: Introductionmentioning
confidence: 99%
“…[39][40][41][42] By grinding powder samples in the crystal state, materials typically convert into the amorphous state; the resulting molecular distribution would thus be randomized, and the degree of intermolecular interactions should be significantly different. As a result, changes in emission color or intensity can thus be observed.…”
Section: Mechanofluorochromic (Mfc) Materialsmentioning
confidence: 99%