Mechanochemistry: Toward green synthesis of metal–organic frameworks

Głowniak, Sylwia; Szczęśniak, Barbara; Choma, J.; Jaroniec, Mietek

doi:10.1016/j.mattod.2021.01.008

Cited by 209 publications

(121 citation statements)

References 129 publications

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“…To date, mechanochemical approaches being applied to transformations from across the chemical sciences have been reported, spanning from the synthesis of inorganic and organic compounds [including those as complex as peptides ( Hernández et al, 2017 ; Maurin et al, 2017 )] through to the preparation of large porous frameworks such as metal-organic frameworks [MOFs( Stolar et al, 2017 ; Stolar and Užarević, 2020 ; Wang et al, 2020 ; Zhou et al, 2020 ; Głowniak et al, 2021 ; Stolar et al, 2021 )]. Moreover, the scale of mechanochemical reactions has ranged from the mechanical manipulation of single atoms and molecules (predominantly, synthetic and natural polymers) using atomic force microscopy ( Kaupp, 2009 ; Ribas-Arino and Marx, 2012 ; Makarov, 2016 ; Li et al, 2017 ) to the induction of reactions in multi-component inorganic and organic powder mixtures in ball milling reactors or extruders ( Iwasaki et al, 2010 ; Am Ende et al, 2014 ; Oliveira et al, 2017 ; Andersen and Mack, 2018b ; Egleston et al, 2020 ).…”

Section: Introductionmentioning

confidence: 99%

Tribochemistry, Mechanical Alloying, Mechanochemistry: What is in a Name?

Michalchuk

Болдырева²,

Belenguer³

et al. 2021

Front. Chem.

135

108

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Over the decades, the application of mechanical force to influence chemical reactions has been called by various names: mechanochemistry, tribochemistry, mechanical alloying, to name but a few. The evolution of these terms has largely mirrored the understanding of the field. But what is meant by these terms, why have they evolved, and does it really matter how a process is called? Which parameters should be defined to describe unambiguously the experimental conditions such that others can reproduce the results, or to allow a meaningful comparison between processes explored under different conditions? Can the information on the process be encoded in a clear, concise, and self-explanatory way? We address these questions in this Opinion contribution, which we hope will spark timely and constructive discussion across the international mechanochemical community.

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Section: Introductionmentioning

confidence: 99%

Tribochemistry, Mechanical Alloying, Mechanochemistry: What is in a Name?

Michalchuk

Болдырева²,

Belenguer³

et al. 2021

Front. Chem.

135

108

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“…In our review, we also omitted the other industrially oriented methods for scalable MOF fabrication, such as electrochemistry, mechanochemistry and microwaveassisted synthesis. The reason for this is the rather high degree of development of these methods, which is reflected in the relevant reviews [76][77][78][79][80][81].…”

Section: Discussionmentioning

confidence: 99%

Metal-Organic Frameworks for Metal-Ion Batteries: Towards Scalability

et al. 2021

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Metal-organic frameworks (MOFs), being a family of highly crystalline and porous materials, have attracted particular attention in material science due to their unprecedented chemical and structural tunability. Next to their application in gas adsorption, separation, and storage, MOFs also can be utilized for energy transfer and storage in batteries and supercapacitors. Based on recent studies, this review describes the latest developments about MOFs as structural elements of metal-ion battery with a focus on their industry-oriented and large-scale production.

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“…Adapted with permission from Ref. 96 Copyright © 2021 Elsevier Ltd. Mechanochemistry has been also utilized to alter physicochemical properties of metal oxides or incorporate diverse metallic species into the frameworks of ordered mesoporous silicas. We believe that mechanochemically obtained mesoporous materials and their employment into practical technologies will emerge soon.…”

Section: Materials Advances Accepted Manuscriptmentioning

confidence: 99%

“…On the other hand, using mechanochemical methods it is difficult to precisely control the synthesis mechanism. Moreover, fast nucleation and limited control over crystals growth may result in the reduced crystallinity and quality of the obtained products.Table 2presents a comparison of typical solvent-based and mechanochemical methods 96.…”

mentioning

confidence: 99%