Mechanochemical Synthesis of Arylsilanes via Barbier‐Type Reaction between Aryl Halides and Chlorosilanes with Magnesium
Lianze Zong,
Ruizhi Sun,
Xixi Hu
et al.
Abstract:The reaction of chlorosilanes with organometallic reagents is an old and well‐developed approach to organosilicon compounds, however , its application was limited due to the sensitivity of organometallic reagents to air, water. Here we display a mechanochemical access to arylsilanes via Barbier‐type reaction of chlorosilanes with aryl halide with magnesium. By treatment of the two halides with Mg powder under electromagnetic milling, a series of arylsilanes are obtained within 15 minutes. Taking the advantages… Show more
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