Mechanistic Insights into the Copper‐Catalyzed Cross‐Dehydrogenative Allylic Alkynylation Reaction
Paul Hünemörder,
Gustavo Alvarez,
Leo Gräber
et al.
Abstract:Allylic functionalization reactions are an important tool for constructing many organic compounds, as they allow for the insertion of the versatile allyl group. Numerous catalytic processes have been developed, primarily utilizing noble metals such as palladium and pre‐functionalized substrates. Conversely, the copper‐catalyzed oxidative C‐H derivatization route, whether thermal or photocatalyzed, remains relatively underdeveloped. This is mostly due to the lack of a general concept and corresponding mechanist… Show more
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