Mechanistic Insights into Cationic [P,O]-Pd-Catalyzed Chain-Transfer Copolymerization of Ethylene with Carbon Monoxide
Wen-Li Zhang,
Shuai Han,
Shi-Huan Li
et al.
Abstract:The copolymerization of olefins with carbon monoxide (CO) affords aliphatic polyketones, which exhibit excellent mechanical strength, crystallinity, photodegradability, hydrophilicity, and surface and barrier properties. The chaintransfer copolymerization of ethylene with CO has offered an available method to regulate the molecular weight of polyketones that are amenable to conventional injection molding and extrusion. In this study, we investigated the copolymerization pathway using the [P,O]-Pd catalyst in a… Show more
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