Mechanistic information from the effect of pressure on the kinetics of some anation reactions of aquopentaamminecobalt(III), -rhodium(III), and -chromium(III) ions in acidic aqueous solution
“…Little agreement was found. Thus Van Eldik et al [25] placed an upper limit of 0.1 M-1 on the equilibrium constant for ion pairing between pentammineaquocobaltate(III) and sulfate ions obtained by kinetic measurements and compared this result with the reported spectroscopic values of 2.9 and 11.2 M -1. The significance of these discrepancies is discussed by Swaddle [5].…”
Section: Formation Constants Structure and Lifetimes Of Outer Smentioning
confidence: 98%
“…They found a value of 670+10 at 24.5°C and ionic strength 0.0094 M. There were a number of subsequent studies using other anions [24][25][26]. The objective was to compare second sphere coordination equilibrium constants obtained by spectroscopic means with those deduced from kinetic measurements assuming an interchange mechanism for anation reactions.…”
Section: Formation Constants Structure and Lifetimes Of Outer Smentioning
“…Little agreement was found. Thus Van Eldik et al [25] placed an upper limit of 0.1 M-1 on the equilibrium constant for ion pairing between pentammineaquocobaltate(III) and sulfate ions obtained by kinetic measurements and compared this result with the reported spectroscopic values of 2.9 and 11.2 M -1. The significance of these discrepancies is discussed by Swaddle [5].…”
Section: Formation Constants Structure and Lifetimes Of Outer Smentioning
confidence: 98%
“…They found a value of 670+10 at 24.5°C and ionic strength 0.0094 M. There were a number of subsequent studies using other anions [24][25][26]. The objective was to compare second sphere coordination equilibrium constants obtained by spectroscopic means with those deduced from kinetic measurements assuming an interchange mechanism for anation reactions.…”
Section: Formation Constants Structure and Lifetimes Of Outer Smentioning
Die Kinetik der Anationsreaktionen A in saurer wäßriger Lösung wird als Funktion der Nucleophilenkonzentration und des Druckes bis 1.5 kbar spektrophotometrisch untersucht.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.