Every year, several tens of million tonnes of polymers end up as waste. Contrary to popular belief and optimistic media stories of ever-improving recycling efforts, only a small fractionindeed, a few percent of this polymeric litter is actually being recycled and reused. In the U.S., some 3 million tonnes of plastics are recycled annually, yet over 28 million tonnes age unproductivelyif the energy of this waste could be harnessed at a moderate 50% efficiency, the greater Chicago area would glow and spark almost all year round! Fortunately, significant progress is being made in technologies that aim at retrieving energy from waste polymers. On the large, often industrial, scales, polymers are being incinerated, pyrolized, and chemically degraded. Some of these technologies can produce viable fuels at costs as low as $0.75 per gallon, some five times smaller than what Mr Smith nowadays pays at the gas pump. There is also plenty of interesting, exploratory science done at smaller scales, where polymers are used in electrostatic or piezoelectric generators, or as materials converting mechanical to chemical energy. Several proof-of-concept devices have been shown to produce enough energy to power personal electronic devices or drive laboratory-scale chemical reactions. Together, the large-and smallscale technologies constitute a realistic strategy to retrieve a sizeable fraction of energy stored in polymers that would otherwise be only presenting a serious environmental concern.
Broader contextOwing to their high caloric content, the millions of tons of polymers we produceand oen discardcould constitute a viable source of energy that can be retrieved by either breaking or rearranging the orientations of constituent chemical bonds. Despite optimistic media reports, we are still harnessing only a small fraction of this energy; in the U.S. alone, some 28 million tons of polymers are simply wasted each year, translating into the loss of almost a trillion MJ of energy that could be put to productive use. This article reviews a wide range of approaches by which energy "hidden" in polymers can be retrieved or transducedexamples range from traditional polymer incineration and chemolysis to the cutting-edge research on triboelectric, piezoelectric or thermoelectric generators with applications in personal electronics, MEMS, and small-scale synthesis. While none of these approaches offers a net-positive energy balance, their synergistic deployment on scales from industrial to personal could amount to societally appreciable energy savings.