The mass transfer limitation of gas products in heterogeneous
photocatalytic
reactors is a key step in governing the reaction efficiency, and the
bubble behavior on the catalyst surface directly affects the mass
transfer process. In this study, a method for the directional regulation
of bubble behavior by the periodic chopping was proposed. The specific
chopping modes drove the bubble to bounce on the photoelectrode surface,
and the growth curve of the bouncing bubble was stepped. The bubble
bouncing characteristics were directionally regulated by adjusting
the chopping mode, and the bubble growth time and detachment diameter
were significantly reduced. A force analysis model of the bubble bouncing
process was established, and a multiphysics simulation of the bubble
bouncing behavior was performed. The competition of forces is the
physical mechanism that drives the bubble to bounce, and the thermal
Marangoni force is the driving force that causes the bubble to return.
The heat and mass transfer processes were dominated by convection,
and the bubble bouncing behavior could significantly enhance convective
transport near the photoelectrode surface. This paper provides an
experimental and theoretical basis for promoting the bubble detachment
and the heat and mass transfer rate on the gas evolving electrode
surface during photoelectrocatalytic conversion.