Mechanism of the decomposition reaction of trans-[Mo(N2)2(PPh2Me)4] and of its reaction with pyridine

Máñez, M. Angeles; Puerta, M. Carmen; Valerga, Pedro; Basallote, Manuel G.

doi:10.1039/dt9920001291

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Mechanism Of Formation Of the Dihydrogen Complex1

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2008

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Cited by 6 publications

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“…and their reactions (10) with a base B are also slow processes, with rate constants that correlate well with the thermodynamic driving force for the reaction and yield excellent Bronsted plots. 17 The kinetic isotope effect observed for these reactions in which the metal hydride acts as the proton donor is normal and close to 3.7, in agreement with values calculated from a weak interaction model.…”

Section: Mechanism Of Formation Of the Dihydrogen Complexmentioning

confidence: 86%