Abstract:Electrochemical reduction of CO2 to value-added chemicals has been hindered by poor product selectivity and competition from hydrogen evolution reactions. This study aims to unravel the origin of the product selectivity and competitive hydrogen evolution reaction on [MP]0 catalysts (M = Fe, Co, Rh and Ir; P is porphyrin ligand) by analyzing the mechanism of CO2 reduction and H2 formation based on the results of density functional theory calculations. Reduction of CO2 to CO and HCOO− proceeds via the formation … Show more
“…22 In this perspective, we focus on our recent efforts in understanding the role of metal/metal-oxide interfaces in heterogenous thermal and electrochemical CO 2 reduction and conversion. [23][24][25][26][27][28][29][30][31][32][33][34][35][36][37][38][39]…”
Converting CO2 to valuable chemicals reduces CO2 emissions and contributes to the “net-zero” goal. This article highlights the crucial role of interfacial sites in effectively catalyzing CO2 activation for thermal and electrochemical CO2 reduction.
“…22 In this perspective, we focus on our recent efforts in understanding the role of metal/metal-oxide interfaces in heterogenous thermal and electrochemical CO 2 reduction and conversion. [23][24][25][26][27][28][29][30][31][32][33][34][35][36][37][38][39]…”
Converting CO2 to valuable chemicals reduces CO2 emissions and contributes to the “net-zero” goal. This article highlights the crucial role of interfacial sites in effectively catalyzing CO2 activation for thermal and electrochemical CO2 reduction.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.