Mechanism and Kinetics of the Induction Period in Nitroxide Mediated Thermal Autopolymerizations. Application to the Spontaneous Copolymerization of Styrene and Maleic Anhydride

Bonilla‐Cruz, José; Caballero, Laura; Albores‐Velasco, Martha; Saldvar-Guerra, Enrique; Percino, M. Judith; Chapela, Víctor M.

doi:10.1002/9783527610860.ch14

Cited by 1 publication

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References 16 publications

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“…The SMAh copolymers are mostly synthesized using free radical polymerization (Scheme 1a). The most commonly used initiators are benzoyl peroxide (BPO) and azo-bis-(isobutyronitrile) (AIBN), while spontaneous initiation [40,42], UV initiation [43], and some other initiators [44] were also reported. The copolymerization could be conducted in bulk and common organic solvents such as THF, DMF, acetone, methyl ethyl ketone, benzene, carbon tetrachloride, benzene and saturated hydrocarbons.…”

Section: Traditional and Controlled Radical Copolymerization For Altementioning

confidence: 99%

Recent advances in alternating copolymers: The synthesis, modification, and applications of precision polymers

Huang

Turner

2017

Polymer

111

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Alternating copolymers represent a special class of copolymers, in which the two comonomers copolymerize in a regular alternating sequence along the chain. Their interesting physical and chemical properties, as well as the underlying mechanism, have attracted significant attention in both academia and industry. The electron-donor benzylidene monomers-styrene and stilbene, readily form alternating copolymers with the electron-acceptor monomersmaleic anhydride and N-substituted maleimides. The rich chemistry of the substitution groups on these monomers offers enormous combinations for the synthesis of alternating copolymers for different applications. In this paper, we aim to provide a general overview of recent publications on the specific field of these benzylidene-containing alternating copolymers, and the emphasis is placed on the synthetic progress, structure-property relationships, and the applications of these copolymers.

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Section: Traditional and Controlled Radical Copolymerization For Altementioning

confidence: 99%

Recent advances in alternating copolymers: The synthesis, modification, and applications of precision polymers

Huang

Turner

2017

Polymer

111

View full text Add to dashboard Cite

show abstract

Mechanism and Kinetics of the Induction Period in Nitroxide Mediated Thermal Autopolymerizations. Application to the Spontaneous Copolymerization of Styrene and Maleic Anhydride

Cited by 1 publication

References 16 publications

Recent advances in alternating copolymers: The synthesis, modification, and applications of precision polymers

Recent advances in alternating copolymers: The synthesis, modification, and applications of precision polymers

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