There is no known method or collection of methods that can recover all of the petroleum from an underground reservoir. Even when several different methods are applied sequentially over a period of decades, on average, they leave about two-thirds of the oil trapped in the reservoir (1).Enhanced oil recovery (EOR) is a collective term for various methods of increasing oil recoveries that have been developed since about 1970. Up until about 1980, the use of surfactants in EOR was more or less synonymous with "micellar/polymer" flooding, in which surfactants are used to decrease the interfacial tension between "oil" and "water" from ~ 10 dyne/cm to ≤ 0.01 dyne/cm. However, the term "surfactant flooding" is now becoming increasingly associated with ways to improve gas and steam flooding, rather than with its earlier usage. In the early 1980's disappointment with micellar/polymer flooding became widespread, as almost all oil being produced by EOR was due to steam flooding. But steam flooding was appropriate only for shallow reservoirs containing viscous, "heavy" oil. Hence, the oil industry turned to "gas" flooding, especially with CO 2 , as the main hope for producing substantially more oil by EOR. Thus, in the early 1980's the industry began to make very large investments in gas-flood EOR, and the results of those investments are just beginning to become known.Because they have very low viscosities (compared to oil), steam, CO 2 , and other gases suffer from a major problem: these injected fluids never make contact with much of the reservoir and the oil it contains, but instead channel more or less directly from injection to production well, leaving the uncontacted oil unproduced.By improving "sweep" and "mobility control," surfactant-based methods offer the most promising ways to alleviate these problems. This use of surfactants appears to be just on the verge of commercialization for steam flooding. Because miscible CO 2 flooding has been commercialized more recently, the use of surfactants to improve gas-flood EOR has not yet been commercialized. Conceivably, however, the long-term viability of gas flooding could prove to be dependent on the success of current research efforts in the use of surfactants to alleviate "bypass" problems.This chapter not subject to U.S.