Mechanically Robust, Durable, and Multifunctional Hyper‐Crosslinked Elastomer Based on Metal–Organic‐Cluster Crosslinker: The Role of Topological Structure
Qi‐Sheng Huang,
Yan Ma,
Yan‐Long Luo
et al.
Abstract:Polymer materials formed by conventional metal‐ligand bonds have very low branch functionality, the crosslinker of such polymer usually consists of 2–4 polymer chains and a single metal ion. Thus, these materials are weak, soft, humidity‐sensitive, and unable to withstand their shape under long‐term service. In this work, a new hyperbranched metal–organic cluster (MOC) crosslinker containing up to 16 vinyl groups is prepared by a straightforward coordination reaction. Compared with the current typical synthesi… Show more
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