2017
DOI: 10.1021/acs.jpcb.6b10705
|View full text |Cite
|
Sign up to set email alerts
|

Mechanically Induced Homochirality in Nucleated Enantioselective Polymerization

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
1
1
1
1

Citation Types

3
18
0

Year Published

2017
2017
2022
2022

Publication Types

Select...
4
3

Relationship

2
5

Authors

Journals

citations
Cited by 17 publications
(21 citation statements)
references
References 59 publications
3
18
0
Order By: Relevance
“…These clays, although present in racemic mixtures, provide excellent justification for enantioselective catalytic mechanisms. Theoretical examples of SMSBs in a LES reaction network siting both of the above-mentioned autocatalysis at two different sites at different temperatures, have been reported for the scenario of deep ocean hydrothermal vents [48].…”
Section: Type Of Thermodynamic Systemmentioning
confidence: 98%
See 2 more Smart Citations
“…These clays, although present in racemic mixtures, provide excellent justification for enantioselective catalytic mechanisms. Theoretical examples of SMSBs in a LES reaction network siting both of the above-mentioned autocatalysis at two different sites at different temperatures, have been reported for the scenario of deep ocean hydrothermal vents [48].…”
Section: Type Of Thermodynamic Systemmentioning
confidence: 98%
“…[44,45]) but also when applied to the preparation of enantiopure organic compounds [46]. Furthermore, it probably also occurs in the self-assembly of achiral compounds to chiral aggregates [47], and theoretically may also occur in polymerizations [48].…”
Section: Viedma Deracemization Mechanismsmentioning
confidence: 99%
See 1 more Smart Citation
“…This suggests that the former results on the homochiral biases reported earlier by Kondepudi, in the formation of strong racemic biases in such types of racemic conglomerates [76,77], could belong to this type of SMSB mechanism. Regarding a generalization of the Viedma deracemization, the increasing number of reports on the spontaneous formation of strong bias from the racemic composition in the self-assembly of achiral building blocks towards chiral aggregates or liquid crystals, is surely significant [78][79][80].…”
Section: Smsb In Enantioselective Autocatalytic Polymerization/depolymentioning
confidence: 99%
“…Viedma-like deracemizations (e.g. [9,[76][77][78][79][80]), that is, cases for which when the boundary conditions disappear allowing the system to equilibrate with its surroundings, racemization cannot occur. The only indisputable example of SMSB in solution is the Soai reaction [7].…”
Section: On the Detection Of Smsb In Low Exergonic Reactions In Solutionmentioning
confidence: 99%