“…However, the final performance of the hydrogels is highly dependent on the inherent properties of aqueous solutions or their precursors. , The interactions between the water molecules and the three-dimensional polymer networks easily result in freezing at lower temperatures or dehydration at high temperatures, which highly restrict the applications of hydrogels as the substrates of flexible devices. , Inspired by cold-tolerant species, researchers have successfully developed many effective strategies to improve the freezing resistance of hydrogels, including introducing polyols, ionic liquids, salts, or modified polymers, and the solvent replacement is one of the most common routes to introduce the heterogeneities. − For instance, after the replacement with various types of polyols, the freezing point of hydrogels decreased from −70 to −80 °C. , The working temperature ranges, in this way, were highly expanded . As-obtained hydrogels are commonly referred to as synthesized organohydrogels, which have received a lot of interest. ,− …”