Mechanical, Structural and Crystallization Properties in Titanate Doped Phosphate Glasses

Shaaban, Kh. S.; Yousef, El Sayed; Mahmoud, Safwat A.; Wahab, E. A. Abdel; Shaaban, E.R.

doi:10.1007/s10904-020-01574-x

Cited by 69 publications

(18 citation statements)

References 46 publications

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“…Under these characteristics glass doped TiO2 has extend applications in the field of optics, photonics, optoelectronics, and telecommunication devices. In glasses, usually TiO2, are intermediate, crystallizing agents and it may be observed in the Ti 4+ and involved in the structural units of TiO4, TiO6 and TiO5 [5][6][7][8][9][10].…”

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confidence: 99%

Optical Properties of SiO2 – TiO2 – La2O3 – Na2O – Y2O3 Glasses and A Novel Process of Preparing the Parent Glass-Ceramics

El‐Rehim

Wahab

Halaka

et al. 2021

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Quaternary glasses with the composition 50SiO2-25TiO2-5La2O3-(20-x) Na2O-xY2O3 where : (0 ≤ ≥ 10) were synthesized using the melt-quench technique. XRD examined the nature of prepared glasses. UV-spectroscopic of investigated glass system studied at room temperature. Both optical bandgap and refractive index of the present glass have been increased. The polarizability and basicity were determined. Thermal parameter values increased as Y2O3 increased. Under controlling heat, the glass-ceramic were prepared and confirmed using XRD. Glass-ceramics are examined using SEM to evaluate a microstructure. Ultrasonic velocities and elastic-moduli of glass-ceramic samples are increased because of the increase in internal energy. The role of Y2O3 modifier in the glass system is clearly demonstrated. Y2O3 also works as an excellent nucleating agent that can induce crystallizations, supporting in the creation of the sub-phase of glass-ceramics.

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confidence: 99%

Optical Properties of SiO2 – TiO2 – La2O3 – Na2O – Y2O3 Glasses and A Novel Process of Preparing the Parent Glass-Ceramics

El‐Rehim

Wahab

Halaka

et al. 2021

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“…In specific, the glass based on B2O3 has become common among a wide variety of glass systems, keeping in mind its glass status, transparency, and multiple physical and chemical properties. Due to the ability of the B to transform its coordination number between 3 and 4 with oxygen supplying with the modification of metal cations, these glasses are considered important [12][13][14][15][16][17][18][19][20][21][22].…”

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confidence: 99%

Optical, thermal and radiation shielding properties of B2O3–NaF–PbO–BaO–La2O3 glasses

Shaaban

Alomairy

Al-Buriahi

2021

J Mater Sci: Mater Electron

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The techniques of melt-quenching were used to generate 53B2O3 -2NaF -27PbO -(20 − )BaO -La2O3 (0 ≤ ≥ 15) . XRD patterns have established the amorphous character of glass samples. There is clear evidence of the role of La2O3 modifier in the glass network. The thermal characteristics were identified to increase with an increase in La2O3 content. Increasing La2O3 increases the linear and non-linear optical bandgap energy and the Urbach energy. By adding La2O3 to the glass samples, the refractive index, molar polarizability, polarizability, and optical basicity are increased. Theoretically, the bulk modulus and the glass transition temperature increase because of the increase in bond strength. The number of bonds per unit increased with the increase in La2O3 content because of the modifier character of La2O3 in the glass samples. Multiple optical parameters ( ∞), ( o),(1) , ( 3) ) and ( 2 ) as a function of linear and non-linear were obtained. The extent of shielding in this article was examined with the increment in La2O3 at the expense of BaO. The results correspond with similar studies conducted previously.

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“…Glasses doped intermediate oxides such as TiO2 and Y2O3 have specific mechanical and optical characteristics such as hardness, elastic moduli, and higher refractive index [15][16][17][18][19][20][21]. It is also significant to observe that the inclusion of Y2O3 improves the capability of UV transmission, enhances thermal stability and chemical durability.…”

Section: Introductionmentioning

confidence: 99%

Spectroscopic Properties and Dispersion Parameters of B2O3 – SiO2 – Bi2O3 – TiO2 – Y2O3 Glasses

Shaaban

2021

Preprint

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Glasses with the chemical formula 52B2O3 – 12SiO2- 26Bi2O3 – (10-x) TiO2 - Y2O3, :(0≤ x ≥ 10), the melt-quench method was used to prepare this glass system. The purpose of this article is to investigate the spectroscopic features of these glasses. The nature of the glass system has been investigated using X-ray diffraction analysis. In the current article, the molar volume acquired decreased while the density and refractive index increased. In the current article, Y2O3 plays an important role and impacts the spectroscopic characteristics of the samples accordingly. For all the present glasses, the optical bandgap is found to be in the semiconducting range. The optical bandgap enhances as Y2O3 rises, while Urbach energy reduces. Molar Refractivity, molar polarization, polarization, and optical basicity decrease with increasing Y2O3 content. Wemple and Didomenico principles were used for calculated the Eo and Ed dispersion. The significance of the Y2O3 modifier in the glass system signifies proved.

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Mechanical, Structural and Crystallization Properties in Titanate Doped Phosphate Glasses

Cited by 69 publications

References 46 publications

Optical Properties of SiO2 – TiO2 – La2O3 – Na2O – Y2O3 Glasses and A Novel Process of Preparing the Parent Glass-Ceramics

Optical Properties of SiO2 – TiO2 – La2O3 – Na2O – Y2O3 Glasses and A Novel Process of Preparing the Parent Glass-Ceramics

Optical, thermal and radiation shielding properties of B2O3–NaF–PbO–BaO–La2O3 glasses

Spectroscopic Properties and Dispersion Parameters of B2O3 – SiO2 – Bi2O3 – TiO2 – Y2O3 Glasses

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