To
obtain a new type of biodegradable material with high toughness
and strength used for fused deposition modeling (FDM) printing, a
series of poly(butylene succinate) (PBS)-based polymer materials was
prepared via blending with polylactide (PLA). The rheological, thermal,
and mechanical properties as well as FDM printing performances of
the blends, such as distortion, cross section, and the interlayer
bond strength, were characterized. The results show that with increasing
PLA content, the blends possess higher melt viscosity, larger tensile
strength, and modulus, which are more suitable for FDM printing. Especially,
when the content of PLA is more than 40%, distortion due to residual
stress caused by volume shrinkage disappears during the printing process
and thus products with good dimensional accuracy and pearl-like gloss
are obtained. The results demonstrate that the blend compositions
with moderate viscosity, low degree of crystallinity, and high modulus
are more suitable for FDM printing. Compared with the low elongation
upon breaking of commercially FDM-printed material, the PBS/PLA blend
materials exhibit a typical ductile behavior with elongation of 90–300%.
Therefore, besides biodegradability, the PBS/PLA blends present excellent
mechanical properties and suitability as materials for FDM printing.
In addition, our study is expected to provide methods for valuating
the suitability of whether a thermoplastic polymer material is suitable
for FDM printing or not.