An investigation has been made on the constitution of the Ti-Al-C system in the range of 15–55 at% Al and of 0.1–1.0 at% C and the temperature range of 1250–450 °C. Equilibria including three compounds TiC, Ti3AlC, and Ti2AlC have been studied and transmission electron microscopy (t.e.m.) observations of ordering reactions in az have been made.