1997
DOI: 10.1002/pen.11821
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Mechanical percolation in cellulose whisker nanocomposites

Abstract: Nanocomposites obtained by casting a mixture of a latex and a n aqueous suspension of cellulose whiskers have been studied. Their mechanical properties (e.g. shear modulus) are found to increase by more than three orders of magnitude in the rubbery state of the polymer matrix, when the whisker content is 6 wt%. This large and unusual effect is discussed on the basis of different types of mechanical models, including semi-phenomenological and numerical finite element calculations. It is concluded that cellulose… Show more

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Cited by 339 publications
(285 citation statements)
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“…They also include semiconductor nanoclusters [11] and others [9]. Nanotubes or whiskers (with dimensions in the nanometer scale and the third forming a larger elongated structure), for example, carbon nanotubes [12] or cellulose whiskers [13,14] are extensively studied as reinforcing phases yielding materials with exceptional properties. The third type of nanocomposites is characterized by only one dimension in the nanometer range.…”
Section: Introductionmentioning
confidence: 99%
“…They also include semiconductor nanoclusters [11] and others [9]. Nanotubes or whiskers (with dimensions in the nanometer scale and the third forming a larger elongated structure), for example, carbon nanotubes [12] or cellulose whiskers [13,14] are extensively studied as reinforcing phases yielding materials with exceptional properties. The third type of nanocomposites is characterized by only one dimension in the nanometer range.…”
Section: Introductionmentioning
confidence: 99%
“…They also include semiconductor nanoclusters [5] and others [3]. Nanotubes or whiskers (with dimensions in the nanometer scale and the third forming a larger elongated structure), for example, carbon nanotubes [6] or cellulose whiskers [7,8], are extensively studied as reinforcing phases yielding materials with exceptional properties. The third type of nanocomposites is characterized by only one dimension in the nanometer range.…”
mentioning
confidence: 99%
“…Relatively low levels of nanocellulose addition tended to create defects in the structure, thus decreasing the elastic modulus. However, amounts greater than 5% yielded a net increase in strength, suggesting the presence of a contiguous network of cellulosic elements within the matrix (Favier et al 1997;Chakroborty et al 2006a,b;Hubbe et al 2008).…”
Section: Maintaining Meso-pore Structurementioning
confidence: 99%