Abstract:Ensuring the material durability of an electrolyte is a prerequisite for the long-term service of all-solid-state batteries (ASSBs). Herein, to investigate the mechanical integrity of a solid polymer electrolyte (SPE) in an ASSB upon electrochemical operation, we have implemented a sequence of quasi-static uniaxial tension and stress relaxation tests on a lithium perchlorate-doped poly (vinyl alcohol) electrolyte, and then discussed the viscoelastic behavior as well as the strength of SPE film during the physi… Show more
“…The stress in a viscoelastic material is determined by its entire strain history, and its stress–strain relationship can be described using the Riemann–Stieltjes convolution form 20 where and are the spherical strain tensor and the deviatoric strain tensor, respectively, K is the bulk modulus, and Γ ( t ) is the stress relaxation modulus function. Their values can be obtained by performing stress relaxation experiments on the LFP cathode.…”
Section: Simulation Methodsmentioning
confidence: 99%
“…Taking this into account, we have reported the physical aging and viscoelastic behavior of a poly(vinyl alcohol) electrolyte and further investigated its potential impact on the mechanical stability of an in-service cell system. 20 Sultanova et al discussed the effect of the viscoplastic behavior of PEO-based electrolytes on damage at the active particle/SE interface in ASSLBs at ambient temperature using the traction–separation law under the assumption of interfacial contact parameters. 21 Although the above studies and the results are fascinating, it is still important to note that experiments on the adhesion performance of PEO–LiX electrolytes and electrodes have rarely been reported so far.…”
Polyethylene oxide (PEO)-based solid polymer electrolytes (SPEs) have good ionic conductivity and flexibility, and is a key component of the all-solid-state lithium batteries (ASSLBs). Therefore, the mechanical integrity of PEO-based...
“…The stress in a viscoelastic material is determined by its entire strain history, and its stress–strain relationship can be described using the Riemann–Stieltjes convolution form 20 where and are the spherical strain tensor and the deviatoric strain tensor, respectively, K is the bulk modulus, and Γ ( t ) is the stress relaxation modulus function. Their values can be obtained by performing stress relaxation experiments on the LFP cathode.…”
Section: Simulation Methodsmentioning
confidence: 99%
“…Taking this into account, we have reported the physical aging and viscoelastic behavior of a poly(vinyl alcohol) electrolyte and further investigated its potential impact on the mechanical stability of an in-service cell system. 20 Sultanova et al discussed the effect of the viscoplastic behavior of PEO-based electrolytes on damage at the active particle/SE interface in ASSLBs at ambient temperature using the traction–separation law under the assumption of interfacial contact parameters. 21 Although the above studies and the results are fascinating, it is still important to note that experiments on the adhesion performance of PEO–LiX electrolytes and electrodes have rarely been reported so far.…”
Polyethylene oxide (PEO)-based solid polymer electrolytes (SPEs) have good ionic conductivity and flexibility, and is a key component of the all-solid-state lithium batteries (ASSLBs). Therefore, the mechanical integrity of PEO-based...
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