2007
DOI: 10.1063/1.2735404
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Mechanical characterization of solution-derived nanoparticle silver ink thin films

Abstract: Mechanical properties of sintered silver nanoparticles are investigated via substrate curvature and nanoindentation methods. Substrate curvature measurements reveal that permanent microstructural changes occur during initial heating while subsequent annealing results in nearly elastic behavior of the thinner films. Thicker films were found to crack upon thermal treatment. The coefficient of thermal expansion was determined from linear slopes of curvature curves to be 1.9± 0.097 ppm/°C, with elastic modulus and… Show more

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Cited by 59 publications
(50 citation statements)
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“…Consequently the thickness at the trace edge is higher than the trace centre. From the literature, crack formations have been reported to occur for thicker films [40] and films which are above a certain critical thickness [41,42]. When the silver overprint was increased to 2 layers, a wider crack area was observed for the smaller traces (100 µm and 500 µm), while the cracks for the 1 mm trace remained at the edges (Figure 3(B)).…”
Section: Cracking In Silver Traces On Emd 6200mentioning
confidence: 96%
See 1 more Smart Citation
“…Consequently the thickness at the trace edge is higher than the trace centre. From the literature, crack formations have been reported to occur for thicker films [40] and films which are above a certain critical thickness [41,42]. When the silver overprint was increased to 2 layers, a wider crack area was observed for the smaller traces (100 µm and 500 µm), while the cracks for the 1 mm trace remained at the edges (Figure 3(B)).…”
Section: Cracking In Silver Traces On Emd 6200mentioning
confidence: 96%
“…The silver traces on the EMD 6200 would experience compressive residual thermal stresses due to the higher CTE of the insulator (60-80 µm °C -1 ) [22] compared to the silver trace (α Ag = 19.6 µm °C -1 ) [10,40]. Furthermore an inhomogeneous stress distribution could have resulted during the solidification of the silver trace, where compression is generated in the bottom-most region (due to the CTE mismatch), while the top-most region could have remained in tension.…”
Section: Cracking In Silver Traces On Emd 6200mentioning
confidence: 99%
“…Nanoporous films usually exhibit different mechanical properties compared to the bulk, especially when the elastic modulus and hardness are considered [18]. Basically, those two parameters have low values that are greatly affected by the porosity as well as by the grain size.…”
Section: Interconnects Reinforcement By Electroless Nickel Platingmentioning
confidence: 99%
“…Mechanical properties of printed structures have been main interests in various engineering applications [123].…”
Section: Insulating Blockmentioning
confidence: 99%