Mechanical Characteristics of As₂S₃Glasses Induced by Doping with Bismuth

Abstract

This paper presents and discusses the results of the instrumented indentation test of the samples of the system Bix(As2S3)100−x, x = 1.5, 3, 5, and 7 at.%. Measurements of mechanical parameters were performed using a Fischerscope HM2000 S nanoindentation device. The experimental data obtained by measuring the microhardness parameters were used to determine some other mechanical quantities that are important for the characterization of the examined materials in terms of their potential applications. For the first three compositions, the results indicated an increase in the microhardness with the increase in the content of doping atoms, which can be interpreted as an enhancement of the strength and stiffness of the structural network. The lower value of microhardness of the sample with the maximum content of Bi can BE associated with the specific structure of this composition. The pronounced indentation size effect was also detected on the indentation curve in the range of smaller loads. According to the model of elastic-plastic deformation, applied for the description of indentation size effect measured for the investigated chalcogenides, the largest value of the elastic recovery was observed for the sample Bi7(As2S3)93.The calculated values of the elasticity modulus show that the glass with x = 5 at.% Bi is characterized with the highest atomic packing density.

Isoconversional Analysis of Thermally Stimulated Effects in Cux(As2Se3)100-x Glasses

“…Chalcogenide glasses, especially those doped with certain elements (Ge, Cu, Ag, Sn, etc. ), show very significant and unique chemical and physical properties, primarily electrical and optical, which, even today, make these materials attractive for scientific research and different applications [1][2][3][4][5]. Opportunities for the application of Cu-doped chalcogenide glasses are wide-ranging due to the possibility of programmed variations of the important thermal, thermo-mechanical, optical, structural, and electronic properties of chalcogenide glasses, induced by Cu introduction [6][7][8][9][10][11].…”