Powder pattern matching techniques, using all the experimentally measured data points, coupled with cluster analysis, fuzzy clustering and multivariate statistical methods are used, with appropriate visualization tools, to analyse a set of 27 powder diffraction patterns of alumina collected at seven different laboratories on different instruments as part of an International Center for Diffraction Data Grant-in-Aid program. In their original form, the data factor into six distinct clusters. However, when a non-linear shift of the form Á 2 a 0 a 1 sin (where a 0 and a 1 are re®nable constants) is applied to optimize the correlations between patterns, clustering produces a large 25-pattern set with two outliers. The ®rst outlier is a synchrotron data set at a different wavelength from the other data, and the second is distinguished by the absence of K 2 lines, i.e. it uses Ge-monochromated incident X-rays. Fuzzy clustering, in which samples may belong to more than one cluster, is introduced as a complementary method of pinpointing problematic diffraction patterns. In contrast to the usual methodology associated with the analysis of round-robin data, this process is carried out in a routine way, with minimal user interaction or supervision, using the PolySNAP software.