Mixing ratios of tropospheric CO as measured by an aircraft-mounted radiometer over Saudi Arabia, the Arabian Sea, and northern India during May and June 1979 are reported. During early May, exceptionally high CO levels were detected over Saudi Arabia, and strong horizontal gradients in CO mixing ratios were seen to develop over a period of several days. Over the Arabian Sea, mixing ratios of the order of 150 parts per billion by volume were observed before the monsoon onset, and a pronounced decrease in CO was detected toward the equator. Subsequent measurements after the monsoon had become established revealed a consistent decrease in CO mixing ratio across this region. Analysis of aircraft dropsonde data and constant pressure daily streamline charts lend strong support to the hypothesis that this reduction is associated with the influx of CO-poor southern hemisphere air in the monsoon southwesterlies.
INTRODUCTIONThe global cycle of atmospheric carbon monoxide is at present poorly understood. This fact is primarily due to the lack of a comprehensive set of global observations with adequate temporal and spatial resolution. The best estimates of the global distribution of CO in the atmosphere to date have been obtained by direct-sampling methods based either aboard ships [Robinson and Robbins, 1968; Lamontagne et al., 1971' Swinnerton and Lamontagne, 1974] or aircraft l-Seiler and Junge, 1970; Seiler and Warneck, 1972; Seiler, 1974; Newell and Gauntnet, 1979; Heidt et al., 1980; Seiler and Fishman, 1981].Such observations have established that the average CO mixing ratio in the northern hemisphere troposphere decreases with altitude and has a maximum value of about 240 ppbv in the surface air at mid-latitudes. In the southern hemisphere troposphere, CO is well mixed vertically, but the mixing ratio increases from about 50-60 parts per billion by volume (ppbv) at high latitudes to almost 100 ppbv near the equator. Much higher CO mixing ratios are often found in the boundary layer near urban and industrial centers in both hemispheres.The major sources and sinks of atmospheric CO have yet to be quantified with a high degree of accuracy. Logan et al. [1981] have made an exhaustive survey both of the CO budget and the tropospheric chemical reactions in which the gas is involved. They find that the oxidation of CH½ (suggested by McConnell et al. [1971]), the oxidation of hydrocarbons [Robinson and Robbins, 1969, Wofsy eta!, 1972, Zimmerman et al., 1978], the burning of biomass [Crutzen et al., 1979], and fossil fuel use constitute the main sources of atmospheric CO on the global scale. It is also possible that arid soils [Conrad and Seiler, 1982] might be a significant source in a region such as North Africa and the Mideast. The main sink of CO is thought to be oxidation by the OH radical I-Weinstock, 1969' Let, y, 1971], but the estimates of the magnitude of the sink are rendered approximate by a large uncertainty in the OH abundance. Oxidation of CO at the surface represents a smaller sink, which is significantly de...