Measurement of Volatile Sulfur Compounds in Beer Using Gas Chromatography with a Sulfur Chemiluminescence Detector

Burmeister, M. S.; Drummond, C.J.; Pfisterer, E. A.; Hysert, D. W.; Sin, Yeong-Min; Sime, K. J.; Hawthorne, D. B.

doi:10.1094/asbcj-50-0053

Cited by 26 publications

(17 citation statements)

References 7 publications

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“…Fifteen of these volatiles: 2-methyl-1-propanol, isoamyl acetate, 3-methyl-1-butanol, ethyl hexanoate, heptyl acetate, ethyl octanoate, octyl acetate, linalool, ethyl decanoate, 3-methyl butanoic acid, 2-phenylethyl acetate, ␤-phenylethanol, octanoic acid and decanoic acid, were detected in all samples (Table 7) but the ratio between the single components were different for each beer. Some of these 15 compounds, such as isoamyl acetate, hepty acetate, octyl acetate, linalool and ␤-phenylethanol, have been reported as common components of different beer types [22,23]. A characteristic GC-qMSD profile of each beer obtained with DVB/CAR/PDMS using the experimental conditions discussed above is shown in Fig.…”

Section: Beer Volatile Profilementioning

confidence: 99%

“…Since the first SPME fibres became commercially available, it has been more and more used and the fields of application have been continuously growing, including a wide range of food analysis, namely the volatile composition of wines [18][19][20][21][22], beers [23,24], whiskys [25][26][27] and several kinds of fruits [28][29][30][31], clinical chemistry [32], environmental chemistry [33,34] and pharmaceutical analysis [35,36], with nowadays about 3000 research papers published.…”

Section: Introductionmentioning

confidence: 99%

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Development of a dynamic headspace solid-phase microextraction procedure coupled to GC–qMSD for evaluation the chemical profile in alcoholic beverages

Rodrigues

Caldeira

Câmara

2008

Analytica Chimica Acta

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t r a c tIn the present study, a simple and sensitive methodology based on dynamic headspace solidphase microextraction (HS-SPME) followed by thermal desorption gas chromatography with quadrupole mass detection (GC-qMSD), was developed and optimized for the determination of volatile (VOCs) and semi-volatile (SVOCs) compounds from different alcoholic beverages:wine, beer and whisky. Key experimental factors influencing the equilibrium of the VOCs and SVOCs between the sample and the SPME fibre, as the type of fibre coating, extraction time and temperature, sample stirring and ionic strength, were optimized. The performance of five commercially available SPME fibres was evaluated and compared, namely polydimethyl- An objective comparison among different alcoholic beverages has been established in terms of qualitative and semi-quantitative differences on volatile and semi-volatile compounds. These compounds belong to several chemical families, including higher alcohols, ethyl esters, fatty acids, higher alcohol acetates, isoamyl esters, carbonyl compounds, furanic compounds, terpenoids, C13-norisoprenoids and volatile phenols. The optimized extraction conditions and GC-qMSD, lead to the successful identification of 44 compounds in white wines, 64 in beers and 104 in whiskys. Some of these compounds were found in all of the examined beverage samples.The main components of the HS-SPME found in white wines were ethyl octanoate (46.9%), ethyl decanoate (30.3%), ethyl 9-decenoate (10.7%), ethyl hexanoate (3.1%), and isoamyl octanoate (2.7%). As for beers, the major compounds were isoamyl alcohol (11.5%), ethyl octanoate (9.1%), isoamyl acetate (8.2%), 2-ethyl-1-hexanol (5.9%), and octanoic acid (5.5%).Ethyl decanoate (58.0%), ethyl octanoate (15.1%), ethyl dodecanoate (13.9%) followed by 3-methyl-1-butanol (1.8%) and isoamyl acetate (1.4%) were found to be the major VOCs in whisky samples.

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Section: Beer Volatile Profilementioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Development of a dynamic headspace solid-phase microextraction procedure coupled to GC–qMSD for evaluation the chemical profile in alcoholic beverages

Rodrigues

Caldeira

Câmara

2008

Analytica Chimica Acta

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“…Since the first SPME fibres becomes commercially available, it has been more and more used and the fields of application have been continuously growing, including a wide range of food analysis, namely the volatile composition of wines [18][19][20][21][22], beers [23], whiskeys [24][25][26], several kinds of fruits [27][28][29][30][31] and honeys [32][33][34][35][36], with nowadays about 3000 research papers published. The technique gained growing acceptance and increasing use in routine laboratories and industrial applications.…”

Section: Introductionmentioning

confidence: 99%

Screening of volatile composition from Portuguese multifloral honeys using headspace solid-phase microextraction-gas chromatography–quadrupole mass spectrometry

Pontes

Marques

Câmara

2007

Talanta

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The volatile composition from four types of multifloral Portuguese (produced in Madeira Island) honeys was investigated by a suitable analytical procedure based on dynamic headspace solid-phase microextraction (HS-SPME) followed by thermal desorption gas chromatography-quadrupole mass spectrometry detection (GC-qMS). The performance of five commercially available SPME fibres: 100 m polydimethylsiloxane, PDMS; 85 m polyacrylate, PA; 50/30 m divinylbenzene/carboxen on polydimethylsiloxane, DVB/CAR/PDMS (StableFlex); 75 m carboxen/polydimethylsiloxane, CAR/PDMS, and 65 m carbowax/divinylbenzene, CW/DVB; were evaluated and compared. The highest amounts of extract, in terms of the maximum signal obtained for the total volatile composition, were obtained with a DVB/CAR/PDMS coating fibre at 60 • C during an extraction time of 40 min with a constant stirring at 750 rpm, after saturating the sample with NaCl (30%). Using this methodology more than one hundred volatile compounds, belonging to different biosynthetic pathways were identified, including monoterpenols, C 13 -norisoprenoids, sesquiterpenes, higher alcohols, ethyl esters and fatty acids. The main components of the HS-SPME samples of honey were in average ethanol, hotrienol, benzeneacetaldehyde, furfural, trans-linalool oxide and 1,3-dihydroxy-2-propanone.

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“…The SCD was employed by Burmeister et al [73] to replace the FPD, the traditional detector for measurement of volatile sulfur compounds in beers, and was found to be sensitive and free from hydrocarbon quenching. Dercksen et al [74,75] reported a method using in-bottle purge-and-trap sampling and GC-SCD that generated a sulfur compound profile correlated to the sulfury notes detected by human panelists.…”

Section: Characterization Of Beers and Other Alcoholic Beveragesmentioning

confidence: 99%

Unique selective detectors for gas chromatography: Nitrogen and sulfur chemiluminescence detectors

Yan¹

2006

J of Separation Science

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ReviewUnique selective detectors for gas chromatography: Nitrogen and sulfur chemiluminescence detectors Many of present day's complex analyses and challenging analytical tasks demand highly selective detection techniques for GC. Universal nitrogen/sulfur chemiluminescence detection is one of the most powerful analytical tools for gas chromatographic analysis. Its strength stems from the unique and beneficial characteristics of high selectivity, sensitivity, and equimolarity. The nitrogen/sulfur chemiluminescence detection technology has provided analytical solutions unsurpassed by any other techniques to a broad range of applications in petroleum characterization, food/beverage flavor analysis, and environmental monitoring. This paper presents a general review of this unique technology, including a brief description of operating principles, an overview of detector performance, practical discussions on instrument operation, and a sizable list of applications.

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Measurement of Volatile Sulfur Compounds in Beer Using Gas Chromatography with a Sulfur Chemiluminescence Detector

Cited by 26 publications

References 7 publications

Development of a dynamic headspace solid-phase microextraction procedure coupled to GC–qMSD for evaluation the chemical profile in alcoholic beverages

Development of a dynamic headspace solid-phase microextraction procedure coupled to GC–qMSD for evaluation the chemical profile in alcoholic beverages

Screening of volatile composition from Portuguese multifloral honeys using headspace solid-phase microextraction-gas chromatography–quadrupole mass spectrometry

Unique selective detectors for gas chromatography: Nitrogen and sulfur chemiluminescence detectors

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