The 'whispering gallery' effect has been known since ancient times for sound waves in air 1,2 , later in water and more recently for a broad range of electromagnetic waves: radio, optics, Roentgen and so on 3-6 . It consists of wave localization near a curved reflecting surface and is expected for waves of various natures, for instance, for atoms 7,8 and neutrons 9 . For matter waves, it would include a new feature: a massive particle would be settled in quantum states, with parameters depending on its mass. Here, we present for the first time the quantum whispering-gallery effect for cold neutrons. This phenomenon provides an example of an exactly solvable problem analogous to the 'quantum bouncer' 10 ; it is complementary to the recently discovered gravitationally bound quantum states of neutrons 11 . These two phenomena provide a direct demonstration of the weak equivalence principle for a massive particle in a pure quantum state 12 . Deeply bound whispering-gallery states are long-living and weakly sensitive to surface potential; highly excited states are short-living and very sensitive to the wall potential shape. Therefore, they are a promising tool for studying fundamental neutron-matter interactions 13-15 , quantum neutron optics and surface physics effects [16][17][18] .The classical whispering-gallery phenomenon can be understood in terms of geometrical optics. Thus, neutron Garland trajectories with a high probability of specular reflection have been observed in curved neutron guides 19 and frequently used in neutron experiments. Elliptical focusing neutron guides using a single reflection are available in commerce. Sound can be reflected in an elliptical chamber from one focus to the other one after 'a single bounce'. A more complex phenomenon consists of wave localization in the vicinity of curved surfaces, also called the whispering-gallery effect. Owing to such localization, the sound can reach a person on the opposite side of a building, or even complete a circle, imitating an 'echo'. Lord Rayleigh explained and described quantitatively this phenomenon in his 'Theory of sound' 1,2 . He verified the theory using a whistle as a sound source and burning candles as the sound intensity 'detectors'. Whales are believed to communicate over long distances, profiting from a similar effect in surface layers of sea water. The electromagnetic whispering-gallery waves from radio to light ('glory' or 'heiligenschein') and Roentgen frequencies are of ever-growing interest 3-6 owing to their multiple applications. They are also known as 'Mie scattering' in light scattering from aerosols and in nuclear physics. An optical analogue of a quantum particle bouncing on a hard surface under the influence of gravity or centrifugal potential has been demonstrated recently using a circularly curved optical waveguide 20 . In all of these cases, a curved mirror acts as a waveguide; and interference of the waves falling to the mirror and those reflected causes specific stationary whispering-gallery modes.For a material wave ...