Measurement of high frequency linear viscoelastic functions of a nitrile‐butadiene rubber compound by ultrasound spectroscopy

Abstract

The storage and loss components of the complex wave modulus, M*(x), measured on a nitrile-butadiene rubber compound (NBR-DIN 53538) by ultrasound spectroscopy at a temperature of 293.2 K, were combined with the components of the complex shear modulus, G*(x), measured on the same sample in a commercial Rheometric Scientific ARES instrument with torsion geometry at different frequencies and temperatures, and superposed in a master plot using the time-temperature superposition principle. From the combined measurements the components of the complex bulk modulus, K*(x), were obtained by means of the exact formula M*(x) ¼ K*(x) þ (4/3)G*(x). Some of the features of the complex bulk modulus reported in the literature for polymeric materials are confirmed for the NBR-DIN mixture. The maxima in G 00 (x) and K 00 (x) are separated by more than one order of magnitude in the frequency scale and furthermore, the shapes of the peaks are different. The simple idea, that, for many polymers, the mechanisms for relaxation in shear and in bulk are of the same basic nature appears not to be supported by the present data. V V C 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 91-102, 2007

Structural Arrest and Thermodynamic Scaling in Filler-Reinforced Polymers

“…Recent studies have highlighted these differences. [57][58][59] Our results for filled PVAc emphasize the difference in the molecular origins for shear and hydrostatic deformation, evident in the very different effects of particle reinforcement.…”