Fiber-matrix interface mechanical properties are the key design point for the composites, however, methodology for evaluating interface properties of C/Cs are not still well established. In this study, capability of the fiber bundle push-out method was demonstrated as a measurement technique of fiber-matrix interfacial mechanical properties of various C/Cs. First, to carefully determine the experimental conditions to give proper interface mechanical properties, the influences of a radius of an indenter and the thickness of specimens on the measured results were examined. From the experimental result, interface debonding stress, τ d , and sliding stress, τ s , could be obtained as a constant value independent from specimen thickness as long as tested using the same indenter size and the proper specimen thicknesses of < 400 µm. However, absolute value of especially τ d showed dependence of on indenter size. This was shown to be the limitation of this method that τ d obtained from this method cannot be treated as a quantitative value. To demonstrate the capability of the method, the change of fiber-matrix interface mechanical properties of C/Cs on the type of fibers and final heat treatment temperature. τ d decreased with the heat treatment temperature in both C/Cs with pitch based carbon fibers, K633 and K321 and C/Cs reinforced with a carbon fiber with higher heat treatment temperature gave lower τ d at the same heat treatment temperature. Main reason for the degradation of τ d up to 2273K was attributed to the enlargement of debonding area at fiber-matrix interface. Degradation of τ d was enhanced at the temperature range of > 2273 K by the structure change of the interface from the graphitization of matrices. Finally, The fiber bundle push-out method was proved to be a strong tool to investigate fiber-matrix interface mechanical properties of C/Cs.