2003
DOI: 10.1016/j.jelechem.2003.08.020
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Measurement of concentration boundary layer thickness development during lithium electrodeposition onto a lithium metal cathode in propylene carbonate

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Cited by 55 publications
(56 citation statements)
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“…Our previous researches discussed the ionic mass transfer rate during the electrodeposition and electrochemical dissolution of Li metal in organic electrolyte (propylene carbonate) by applying the holographic interferometry [6][7][8]. This optical technique successfully visualized the development of Li + concentration profile in agreement with the theoretical prediction, while an apparent incubation period was caused by a chemical reaction between the electrodeposited Li metal and chemical species in electrolyte in the initial stage of electrodeposition.…”
Section: Introductionmentioning
confidence: 73%
“…Our previous researches discussed the ionic mass transfer rate during the electrodeposition and electrochemical dissolution of Li metal in organic electrolyte (propylene carbonate) by applying the holographic interferometry [6][7][8]. This optical technique successfully visualized the development of Li + concentration profile in agreement with the theoretical prediction, while an apparent incubation period was caused by a chemical reaction between the electrodeposited Li metal and chemical species in electrolyte in the initial stage of electrodeposition.…”
Section: Introductionmentioning
confidence: 73%
“…In the authors' group, electrodeposition of Li has been studied onto a Li metal plate in LiClO 4 -PC electrolyte [20,21]. An incubation period appeared during the first few seconds after starting the electrolysis.…”
Section: Discussionmentioning
confidence: 99%
“…The concentration and velocity profiles formed along vertical plane Cu electrodes are measured in-situ by the holographic interferometer and the tracer technique [14][15][16]. Fig.…”
Section: Experimental Systemmentioning
confidence: 99%