Measurement and thermodynamic analysis of the solubility of iodine-containing organoaluminum supported by nitrogenous ligands in pure solvents

Solid–Liquid Equilibrium and Thermodynamic Analysis of Transition Metal Complexes Supported by Bis(imino)pyridine in Different Solvents

“…The δ d , δ P , and δ h of the solvent can be found in the literature; − the HSPs of the solute can be calculated by the following formula: δ d = ∑ F di V δ p = ∑ F pi 2 V δ h = ∑ E hi V where the term F d i is the contribution to the dispersive force of component i . F p i is the contribution to the polar force of component i .…”

“… a Taken from refs and b N represents the frequency of occurrence of the group. F d i is the contribution to the dispersive force of component i .…”

“…Δ u 12 and Δ u 21 are binary cross-interaction parameters. The volume and surface area parameters of solvent were obtained by searching the relevant literature. ,, The values R and Q for L 1 can also be found in the literature . The parameters are showed in Tables and . r i = ∑ i R i V vw = 280.86 cm 3 · mol − 1 15.17 cm 3 · mol − 1 = 18.5142 q i = ∑ i Q i A vw = 40.55 × 10 9 cm 2 · m o l − 1 2.5 × 10 9 cm 2 · mol − 1 = 16.22 …”

“… a r is the volume parameter, and q is the surface area parameter. All the values of r and q for above solvents were taken from refs , , and . …”

Determination of Solubility and Thermodynamic Analysis of Iron(III) β-Diketonate Compounds in Pure Solvents

“…The solid–liquid equilibrium theory is relevant to the solvent selection process. An essential subject of research for the equilibrium of solute–solvent and solute–solute interactions is the solid–liquid phase equilibrium theory . Solubility data is one of the essential parameters of solid–liquid phase equilibrium theory and serves as the foundation for practical procedures such as compound synthesis, separation, and participation in reactions. − Solubility is the mass of the solute that can be dissolved when a solution is saturated at a given temperature.…”